Intext Exercise
Question 1:
In a reaction, 5.3g of sodium carbonate reacted with 6g of ethanoic acid. The products were
2.2g of carbon dioxide, 0.9g water and 8.2g of sodium ethanoate. Show that these observations are in agreement with the law of conservation of mass.
Sodium carbonate + ethanoic acid → sodium ethanoate + carbon dioxide + water
Solution 1:
Sodium
Ethanoi
⎯⎯→
Sodium
Carbon
Water
carbonate acid ethanoate dioxide
Na2 CO3
Given,
CH3COOH
⎯⎯→CH3COONa
CO2
H 2O
Mass of sodium carbonate = 5.3 g
Mass of ethanoic acid = 6 g
Mass of sodium ethanoate = 8.2 g Mass of carbon dioxide = 2.2 g Mass of water = 0.9 g
Now, total mass before the reaction = (5.3 + 6) g = 11.3 g
And, total mass after the reaction = (8.2 + 2.2 + 0.9) g = 11.3 g
∴Total mass before the reaction = Total mass after the reaction
Hence, this is in agreement with the law of conservation of mass.
Question 2:
Hydrogen and oxygen combine in the ratio of 1:8 by mass to form water. What mass of oxygen gas would be required to react completely with 3 g of hydrogen gas?
Solution 2:
In water,
H:O (by mass) =1:8
Then,
The mass of oxygen gas required to react completely with 1 g of hydrogen gas = 8 g.
So, the mass of oxygen gas required to react completely with 3 g of hydrogen gas = (8 × 3) g
= 24 g
Question 3:
Which postulate of Dalton’s atomic theory is the result of the law of conservation of mass?
Solution 3:
The postulate of Dalton’s atomic theory which is based on the law of conservation of mass is: “Atoms are indivisible particles, which can neither be created nor destroyed in a chemical reaction.”
Question 4:
Which postulate of Dalton’s atomic theory can explain the law of definite proportions?
Solution 4:
The postulate of Dalton’s atomic theory which is based on the law of definite proportion is:
“The elements consist of atoms having fixed mass and that the number and kind of atoms of each element in a given compound is fixed.”
Intext Exercise 2
Question 1:
Define atomic mass unit.
Solution 1:
Mass unit equal to exactly one-twelfth 1
12th
the mass of one atom of carbon-12 is called
one atomic mass unit. It is represented by as ‘a.m.u.’ or ‘u’.
Question 2:
Why is it not possible to see an atom with naked eyes?
Solution 2:
The size of an atom is too small which is not possible to see it with naked eyes. To see an atom we need advanced machines.
Intext Exercise 3
Question 1:
Write down the formulae of
(i) sodium oxide
(ii) aluminium chloride
(iii) sodium sulphide
(iv) magnesium hydroxide
Solution 1:
(i) Sodium oxide: Na2O
(ii) Aluminium chloride: AlCl3
(iii) Sodium sulphide: Na2S
(iv) Magnesium hydroxide: Mg(OH)2
Question 2:
Write down the names of compounds represented by the following formulae: (i) Al2(SO4)3
(ii) CaCl2 (iii) K2SO4 (iv) KNO3 (v) CaCO3
Solution 2:
(i) Al2(SO4)3 : Aluminium sulphate
(ii) CaCl2 : Calcium chloride
(iii) K2SO4 :Potassium sulphate
(iv) KNO3 : Potassium nitrate
(v) CaCO3 : Calcium carbonate
Question 3:
What is meant by the term chemical formula?
Solution 3:
The chemical formula of a compound is the symbolic representation of the composition of a compound. The chemical formula of a compound, tells us that the number and kinds of atoms of different elements that constitute the compound.
For example, from the chemical formula H2O of water, we come to know that one oxygen atom and two hydrogen atoms are chemically bonded together to form one molecule of the
compound, water.
Question 4:
How many atoms are present in a
(i) H2S molecule and (ii) PO3 − ion? Solution 4:
(i) In H2S molecule, total 3 atoms are present of which two hydrogen atoms and one sulphur
atom.
(ii) In
atoms.
PO3 − ion, total 5 atoms are present of which one phosphorus atom and four oxygen
Intext Exercise 4
Question 1:
Calculate the molecular masses of H2, O2, Cl2, CO2, CH4, C2H6, C2H4, NH3, CH3OH.
Solution 1:
Molecular mass of H2 = 2 × Atomic mass of H
= 2 × 1u
= 2 u
Molecular mass of O2 = 2 × Atomic mass of O
= 2 × 16 u
= 32 u
Molecular mass of Cl2 = 2 × Atomic mass of Cl
= 2 × 35.5 u
= 71 u
Molecular mass of CO2 = Atomic mass of C + 2 × Atomic mass of O
= (12 + 2 × 16) u
= 44 u
Molecular mass of CH4 = Atomic mass of C + 4 × Atomic mass of H
= (12 + 4 × 1) u
= 16 u
Molecular mass of C2H6 = 2 × Atomic mass of C + 6 × Atomic mass of H
= (2 × 12 + 6 × 1) u
= 30 u
Molecular mass of C2H4 = 2 × Atomic mass of C + 4 × Atomic mass of H
= (2 × 12 + 4 × 1) u
= 28 u
Molecular mass of NH3 = Atomic mass of N + 3 × Atomic mass of H
= (14 + 3 × 1) u
= 17 u
Molecular mass of CH3OH = Atomic mass of C + 4 × Atomic mass of H + Atomic mass of O
= (12 + 4 × 1 + 16) u
= 32 u
Question 2:
Calculate the formula unit masses of ZnO, Na2O, K2CO3, given atomic masses of Zn
= 65 u, Na = 23 u, K = 39 u, C = 12 u, and O = 16 u.
Solution 2:
Formula unit mass of ZnO = Atomic mass of Zn + Atomic mass of O
= (65 + 16) u
= 81 u
Formula unit mass of Na2O = 2 × Atomic mass of Na + Atomic mass of O
= (2 × 23 + 16) u
= 62 u
Formula unit mass of K2CO3 = 2 × Atomic mass of K + Atomic mass of C + 3 × Atomic mass of O
= (2 × 39 + 12 + 3 × 16) u
= 138 u
Intext Exercise 5
Question 1:
If one mole of carbon atoms weighs 12 gram, what is the mass (in gram) of 1 atom of carbon?
Solution 1:
One mole of carbon atoms weighs 12 g (Given) Thus, the mass of 1 mole of carbon atoms = 12 g
Then, mass of 6.022 1023
number of carbon atoms = 12 g
12
Therefore, mass of 1 atom of carbon g
6.022 1023
1.9927 10−23 g
Question 2:
Which has more number of atoms, 100 grams of sodium or 100 grams of iron (given, atomic mass of Na = 23 u, Fe = 56 u)?
Solution 2:
Atomic mass of Na = 23 u (Given) Then, gram atomic mass of Na = 23 g
Now, 23 g of Na contains = 6.022 1023
number of atoms
6.022 1023
Thus, 100 g of Na contains 100
23
number of Na atoms
= 2.6182 1024 number of Na atoms
Again, atomic mass of Fe = 56 u(Given) Then, gram atomic mass of Fe = 56 g
Now, 56 g of Fe contains = 6.022 1023
number of atoms
6.022 1023
Thus, 100 g of Fe contains 100
56
number of Fe atoms
1.0753 1024
2.6182 1024 1.07531024
number of Fe atoms
Therefore, 100 grams of sodium contain a greater number of atoms than 100 grams of iron.
NCERT Exercise
Question 1:
A 0.24 g sample of compound of oxygen and boron was found by analysis to contain 0.096 g of boron and 0.144 g of oxygen. Calculate the percentage composition of the compound by weight.
Solution 1:
Mass of boron = 0.096 g (Given) Mass of oxygen = 0.144 g (Given) Mass of sample = 0.24 g (Given)
The percentage of boron by weight in the compound 0.096 100%
0.24
= 40%
And, percentage of oxygen by weight in the compound 0.144 100%
0.24
= 60%
Question 2:
When 3.0 g of carbon is burnt in 8.00 g oxygen, 11.00 g of carbon dioxide is produced. What mass of carbon dioxide will be formed when 3.00 g of carbon is burnt in 50.00 g of oxygen? Which law of chemical combinations will govern your answer?
Solution 2:
Carbon + Oxygen ⎯⎯→ Carbon dioxide
3 g of carbon reacts with 8 g of oxygen to produce 11 g of carbon dioxide.
If 3 g of carbon is burnt in 50 g of oxygen, then 3 g of carbon will react with 8 g of oxygen to form11 g of carbon dioxide.
The remaining (50 –8) = 42 g of oxygen will be left unreacted. The above answer is governed by the law of constant proportions.
Question 3:
What are polyatomic ions? Give examples?
Solution 3:
A polyatomic ion is a group of atoms carrying a charge either positive or negative. For
example, ammonium ion NH4 , hydroxide ion (OH ), carbonate ion , CO
sulphate ion
SO2 − .
- 2 −
3
Question 4:
Write the chemical formulae of the following: (a) Magnesium chloride
(b) Calcium oxide
(c) Copper nitrate
(d) Aluminium chloride (e) Calcium carbonate Solution 4:
(a) Magnesium chloride: MgCl2
(b) Calcium oxide: CaO
(c) Copper nitrate: Cu (NO3)2 (d) Aluminium chloride: AlCl3 (e) Calcium carbonate :CaCO3
Question 5:
Give the names of the elements present in the following compounds: (a) Quick lime
(b) Hydrogen bromide
(c) Baking powder
(d) Potassium sulphate
Solution 5:
Compound Chemical formula Elements present
Quick lime CaO Calcium, oxygen
Hydrogen bromide HBr Hydrogen, bromine
Baking powder NaHCO3 Sodium, hydrogen, carbon, oxygen
Potassium sulphate K2SO4 Potassium, sulphur, oxygen
Question 6:
Calculate the molar mass of the following substances: (a) Ethyne, C2H2
(b) Sulphur molecule, S8
(c) Phosphorus molecule, P4 (atomic mass of phosphorus = 31) (d) Hydrochloric acid, HCl
(e) Nitric acid, HNO3
Solution 6:
(a) Molar mass of ethyne, C2H2 = 2 × 12 + 2 × 1 = 28 g/mol
(b) Molar mass of sulphur molecule, S8 = 8 × 32 = 256 g/mol
(c) Molar mass of phosphorus molecule, P4 = 4 × 31 = 124 g/mol (d) Molar mass of hydrochloric acid, HCl = 1 + 35.5 = 36.5 g/mol (e) Molar mass of nitric acid, HNO3 = 1 + 14 + 3 × 16 = 63 g/mol
Question 7:
What is the mass of:
(a) 1 mole of nitrogen atoms?
(b) 4 moles of aluminium atoms (Atomic mass of aluminium = 27)? (c) 10 moles of sodium sulphite (Na2SO3)?
Solution 7:
(a) The mass of 1 mole of N- atoms = 14 g.
(b) The mass of 4 moles of Al-atoms = (4 × 27) g [Atomic mass of Al= 27 u]
= 108 g
(c) The mass of 10 moles of sodium sulphite (Na2SO3)
= 10 × [2 × 23 + 32 + 3 × 16] g (Atomic mass of Na = 23 u, Atomic mass of S=32 u Atomic mass of O = 16 u)
= 10 × 126 g = 1260 g
Question 8:
Convert into mole.
(a) 12 g of oxygen gas
(b) 20 g of water
(c) 22 g of carbon dioxide
Solution 8:
(a) 32 g of oxygen gas = 1 mole
Then, 12 g of oxygen gas = 12
32
moles
= 0.375 mole
(b) 18 g of water (H2O) = 1 mole
20
Then, 20 g of water (H2O) =
18
moles = 1.11 moles (approx.)
(c) 44 g of carbon dioxide (CO2) = 1 mole
Then, 22 g of carbon dioxide (CO ) = 22
44
mole = 0.5 moles
Question 9:
What is the mass of:
(a) 0.2 mole of oxygen atoms?
(b) 0.5 mole of water molecules?
Solution 9:
(a) Mass of 1 mole of oxygen atoms = 16 g
Then, mass of 0.2 mole of oxygen atoms = 0.2 × 16g = 3.2 g
(b) Mass of 1 mole of water molecules (H2O) = 18 g
Then, mass of 0.5 mole of water molecules (H2O) = 0.5 × 18 g = 9 g
Question 10:
Calculate the number of molecules of sulphur (S8) present in 16 g of solid sulphur.
Solution 10:
1 mole of solid sulphur (S8) = 8 × 32 g = 256 g
i.e., 256 g of solid sulphur contains = 6.022 × 1023 molecules
6.022 1023
Then, 16 g of solid sulphur contains
16
256
molecules
= 3.76 × 1022 molecules
Question 11:
Calculate the number of aluminium ions present in 0.051 g of aluminium oxide. (Hint: The mass of an ion is the same as that of an atom of the same element. Atomic mass of Al = 27 u)
Solution 11:
Given, atomic mass of Al = 27 u, atomic mass of O = 16 u
1 mole of aluminium oxide (Al2O3) = (2 × 27 + 3 × 16) = 102 g i.e., 102 g of Al2O3 = 6.022 × 1023 molecules of Al2O3
6.022 1023
Then, 0.051 g of Al2O3 contains =
102
0.051 molecules of Al2O3
= 3.011 × 1020 molecules of Al2O3
The number of aluminium ions (Al3+) present in 1 molecule of aluminium oxide is 2. Therefore, the number of aluminium ions (Al3+) present in 3.011 × 1020 molecules (0.051 g) of aluminium oxide (Al2O3) = 2 × 3.011 × 1
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